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Title:

Activated Carbon Catalytic Supercritical Water Gasification of Glycine

Author(s):

Samanmulya, T., Kanna, M., Matsumura, Y.

Document(s):

Paper Paper

Abstract:

Supercritical water gasification (SCWG) of glycine was studied in a tubular flow reactor which has the inside diameter of 2.17 mm and the length of 12 m. The experiments were carried out at 500­650 oC, 25 MPa with residence times in a range of 63­188 s. Activated carbon of 0.5 wt% was used as a catalyst. The results showed that the increase of temperature and residence time enhanced the gasification efficiency. Although, higher concentration resulted in lower gasification efficiency, at glycine concentration of 1.0 wt%, first order reaction could be assumed. Activated carbon was not effective for glycine gasification. Pre­exponential factor of 2.73×104 s­1 and activation energy of 106.9 kJ/mol were obtained.

Keywords:

biomass, hydrogasification, proteins, reactivity

Topic:

R&D on Biomass Conversion Technologies for Heating, Electricity and Chemicals

Subtopic:

Gasification for synthesis gas production

Event:

21st European Biomass Conference and Exhibition

Session:

2CV.3.36

Pages:

849 - 850

ISBN:

978-88-89407-53-0

Paper DOI:

10.5071/21stEUBCE2013-2CV.3.36

Price:

FREE