Title:
Further Development and Application of Aerosol-Based Method for On-Line Investigation of Char Reactivity in Steam
Author(s):
Lin, L., Strand, M.
Document(s):
Paper
Poster
Abstract:
Wood char was prepared from wood pellets under controlled pyrolysis conditions. The gasification kinetics for wood char in 33 vol% steam was established in the temperature range from 800ºC to 1300ºC by the combination of thermogravimetric analysis (TGA) and a novel aerosol-based method. The aerosol method was further developed and demonstrated successfully for generating, transporting and gasifying the suspended char particles (0.5-10 µm) in the steam atmosphere at high temperature up to 1300ºC. A tapered element oscillating microbalance (TEOM) was used to measure the change of mass concentrations of particles in the carrier gas, before and after gasification. The activation energy was 155 kJ·mol-1 for wood char with the pre-exponential factor of 3.56×104. This method can be potentially applied to on-line measure the reactivity of char particles directly in hot gas from the gasifier.
Keywords:
biomass, kinetics, steam, biochar, aerosol, particles
Topic:
R&D on Biomass Conversion Technologies for Heating, Electricity and Chemicals
Subtopic:
Gasification for synthesis gas production
Event:
21st European Biomass Conference and Exhibition
Session:
2CV.3.50
Pages:
875 - 878
ISBN:
978-88-89407-53-0
Paper DOI:
10.5071/21stEUBCE2013-2CV.3.50
Price:
FREE