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Title:

Experimental Verification of Chemical Pre-Treatments to Increase Biohydrogen Production from Fruit and Vegetable Organic Refuses

Author(s):

Tommasi, T., Ruggeri, B.

Document(s):

Paper Paper

Abstract:

Objectives of the paper are: to evaluate the opportunity to increase the dark bioH2 production from vegetables waste by mechanical pre-treatment followed by acid or basic treatment and to verify the feasibility and reproducibility of H2 production using vegetable bio-wastes taken along yearly seasons. The bio-waste material was taken from the local fruit and vegetable market of large populated city. It was first weighed, cut in small pieces and then homogenized by a kitchen blade mixer. After that, the waste was treated by acid and base for 24 h at 30 °C in a thermostatic chamber. To evaluate the efficacy into produce hydrogen each pre-treated portion were inoculated with Hydrogen Forming Bacteria (HFB) consortium and the hydrogen production was monitored during time. The pre­ treatment with a base resulted to be the more efficient. A test under pH-controlled condition of organic refuse was performed by a stirred-batch reactor STR (Minifors HT, Switzerland) with 2 litres in order to evaluate the energy production as hydrogen. A comparison with a test of glucose under the same conditions shows that the organic refuse is able to produce a quantity of energy of 77 % of that of glucose equal to 14.6 L H2/ kgrwaste. The results, in our opinion, shows the feasibility to use vegetables and fruits wastes pre-treated with alkaline chemicals as suitable substrate for bioH2 production; in addition, with a view to work in full-scale the alkaline pre-treatment prevents a large consume of base-solution during fermentation due to continue acids formation towards a general sustainability of the whole process.

Keywords:

organic waste, chemical pretreatment, hydrogen bioenergy

Topic:

Biological conversion - Fermentation, enzymatic processes

Subtopic:

Biological conversion - fermentation, enzymatic processes

Event:

18th European Biomass Conference and Exhibition

Session:

VP2.6.24

Pages:

1417 - 1422

ISBN-13:

978-88-89407-56-1

ISBN-10:

88-89407-56-5

Paper DOI:

10.5071/18thEUBCE2010-VP2.6.24

Price:

FREE